Palladium, Darling Of The PGEs, Is Shifting Into High Gear

 | Apr 14, 2019 03:16AM ET

The platinum group of elements (PGEs) consist of six metallic elements found in the Periodic Table: iridium (Ir), osmium (Os), palladium (Pd), platinum (Pt), rhodium (Rh) and ruthenium (Ru). Platinum and palladium are the most well-known of the PGEs due to their industrial applications in diesel and gasoline engines. The market for palladium has become especially interesting of late, with the price of the silvery-white metal gaining 18% in 2018, an otherwise down year for metals. Scaling an uncharted $1,600 per ounce in March, palladium is up 70% from a year ago.

We’ll get into the reasons for that in this article, and much more, as we dig deep into the world of PGEs.

Characteristics

PGEs share similar physical and chemical properties, and they usually occur together in the same orebodies. The similarities include a resistance to corrosion, high melting points, and catalytic qualities, meaning they speed up chemical reactions without themselves being chemically altered.

PGEs are the densest of the metallic elements, and they are highly durable. This, along with their high value because of their rarity, make them ideal candidates for recycling.

The first known mining of platinum and palladium alloys is thought to have occurred in pre-Columbian South America (Colombia and Ecuador), where indigenous people mined them from stream sediments and shaped them into jewelry. According to the US Geological Survey (USGS), after 1500 the Spaniards, upon finding platinum grains mixed with gold nuggets in stream deposits, named the metal “platina” meaning “small silver”. However it was considered to be a worthless impurity. Platinum was named a new metal in 1750, followed by the rest of the PGE group, in the early 1800s.

Geology

PGEs are among the rarest of elements in the Earth’s crust . The crust has just 0.0005 parts per million (ppm) platinum for example, compared to 60 million ppm copper and 0.075 Mppm silver and 0.004 Mppm gold.

Over 100 minerals contain components of PGEs, but they are too small to see with the naked eye. Their presence must generally be confirmed by lab analysis. Most PGEs are concentrated in magmatic ore deposits, formed millions of years ago when magma flowed up from Earth’s mantle, cooled and crystallized. Through this process, PGE-rich sulfides accumulated to form PGE deposits. When PGE-enriched rocks eroded, through the movement of water, PGE-enriched placer deposits formed.

Uses of PGEs

The leading use of PGEs is in catalytic converters. These essential automobile components scrub tailpipe emissions in gas or diesel-fueled vehicles.

Palladium is an ingredient in catalytic converters for gasoline-powered cars, vans and trucks; platinum is in the catalytic converters of diesel vehicles. Autocatalyst demand accounts for three-quarters of palladium demand. Twenty-five to 50% of palladium is routinely substituted for platinum in catalytic converters, due to its normally lower price. However that is now reversed, with the price of palladium about double that of platinum. If that dynamic stays the same, carmakers will substitute platinum for higher-priced palladium.

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I was surprised to read that, according to the International Platinum Group Metals Association (IPA), one-quarter of all manufactured goods either contain a PGE, or a PGE played a key role in its production. That makes PGEs indispensable for industrial applications.

The chemical industry for example needs platinum or platinum-rhodium alloys to make specialty silicones and nitric oxide - the raw material in fertilizers, explosives and nitric acid. Platinum-supported catalysts are used to refine crude oil and to produce high-octane gasoline. They are also heavily applied in electronics, with PGE components utilized to increase storage capacities in computer hard disk drives, in multilayer ceramic capacitors, and hybridized integrated circuits. PGEs are needed to produce fiberglass, liquid-crystal and flat-panel displays.

Platinum and iridium’s non-corrosive qualities make them ideal for medical implants such as pacemakers, and surgical tools. Palladium, platinum and rhodium are also investment metals, bought and sold as bars, coins or ETFs.

An emerging market for platinum is in the manufacture of hydrogen fuel cells. Platinum is used to spur the chemical reaction of hydrogen with oxygen. Recognized as powering NASA’s 1969-72 moon landers, the process produces electricity and water. In the case of a fuel-cell electric vehicle, hydrogen is stored in a fuel tank before it is mixed with oxygen from the air.

Platinum demand for hydrogen fuel cells is set to increase into the 2020s, according to a report from Heraeus Precious Metals :

"Several thousand ounces of platinum are used annually and this will grow as the technology is rolled out, potentially exceeding 100,000 ounces per year in the late 2020s."

Market for PGEs

Out of 69 million tonnes of PGEs found worldwide, South Africa’s Bushveld Complex has the largest reserves of platinum and palladium - 63 million tonnes as of 2018, according to the USGS . Russia and Zimbabwe are a respective second and third. The US Geological Survey notes that about 104,000 tonnes of PGEs could be developed throughout the world.

South Africa is also far and away the largest Pt and Pd producer in the world, outputting 178,000 tonnes combined last year. Canada is a significant producer of PGEs, mining and processing 17,000 tonnes of palladium and 9,500 tonnes of platinum in 2018.